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Study of the kinetics of geminal recombination of triplet radical pairs including the ketyl radical and radical cation in micelles of sodium dodecyl sulfate by laser photolysis

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A model of geminal recombination of radical pairs generated in the triplet state in micelles including triplet-singlet transitions in radical pairs, caused by isotropic and anisotropic hyperfine interactions with strong separation of radicals and spin-orbital interaction for contact radical pairs, was proposed.

  2. 2.

    The spin-orbital interaction determines the rate of recombination of triplet radical pairs in micelles of small radius in strong magnetic fields. The contribution of the spinorbital interaction increases on incorporation of heavy atoms in the radicals.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    P. P. Levin & V. A. Kuz'min

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  1. P. P. Levin
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  2. V. A. Kuz'min
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 298–304, February, 1988.

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Levin, P.P., Kuz'min, V.A. Study of the kinetics of geminal recombination of triplet radical pairs including the ketyl radical and radical cation in micelles of sodium dodecyl sulfate by laser photolysis. Russ Chem Bull 37, 224–230 (1988). https://doi.org/10.1007/BF00957414

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  • DOI: https://doi.org/10.1007/BF00957414

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