Conclusions
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1.
A method has been developed for the intercalation of solid substances from solutions in organic solvents into graphite fluoride C2Fx.
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2.
Molecules of inserted paramagnetic copper complexes and nitroxyl radicals assume oriented positions between the structural layers in graphite fluoride.
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3.
The planes of molecules of bis-chelate Cu(II) complexes with acetylacetone, o-hydroxyquinoline, and phenylsalicylaldimine were determined to lie parallel to the C2Fx planes.
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4.
A method has also been suggested for the preparation of samples from C2Fx·yA compounds with a higher degree of texturizing (more nearly complete orientation) than can be achieved by pelletizing.
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N. F. Yudanov and I. I. Yakovlev, Abstracts, 7th All-Union Symposium on the Chemistry of Inorganic Fluorides, Dushanbe [in Russian], Nauka, Moscow,(1984).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 272–276, February, 1988.
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Yudanov, N.F., Boguslavskii, E.G., Yakovlev, I.I. et al. Intercalation of paramagnetic compounds in graphite fluoride with the composition C2Fx . Russ Chem Bull 37, 200–203 (1988). https://doi.org/10.1007/BF00957409
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DOI: https://doi.org/10.1007/BF00957409