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Atranes

XIX. Metalloatrane-3,7,10-triones derived from multivalent metals

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Genetal methods are described for the preparation of metalloatrane-3,7,10-triones

, containing an atom of a ter-, quarter-, or quinquevalent metal (mainly in the form of hydrates). Seven intramolecular compounds of this type (with M = NdIII, ClTiIV, ClZrIV, CeIII, HOPbIV, HOMnIV, HOOUVI), have been prepared, of which only two (with M = NdIII and HOOUVI) were known previously. Compounds with the composition N (CH2COO)3M · mN (CH2COO)3 · nH2O with M = NdIII, ThIV, COIII and NiIII (m=1) and with M = Sb (m=3 and 4) have also been obtained.

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Authors and Affiliations

  1. Institute of Organic Synthesis AS LatvSSR, Riga

    M. G. Voronkov & S. V. Mikhailova

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  1. M. G. Voronkov
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  2. S. V. Mikhailova
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For part XVIII, see [1].

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Voronkov, M.G., Mikhailova, S.V. Atranes. Chem Heterocycl Compd 5, 587–589 (1969). https://doi.org/10.1007/BF00957364

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  • DOI: https://doi.org/10.1007/BF00957364

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