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Investigations in the field of the reactions of cyclene α-oxides

V. Reaction of 1-vinylcyclohex-3-ene dioxide with carboxylic acids

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reaction of 1-vinylcyclohex-3-ene dioxide with carboxylic acids (acetic, propionic, butyric, and monochloroacetic) is described. On the basis of IR spectra, it has been shown that in the reactions without a catalyst the carboxylic acids add mainly to the epoxyethyl group of the molecule of the dioxide, while in the presence of FeCl3 as catalyst a mixture of isomers with epoxyethyl and epoxycyclohexane groups in a ratio of 55∶54 is obtained.

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For part IV, see [4].

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Mukhamedova, L.A., Malyshko, T.M., Shagidullin, R.R. et al. Investigations in the field of the reactions of cyclene α-oxides. Chem Heterocycl Compd 5, 569–571 (1969). https://doi.org/10.1007/BF00957357

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  • DOI: https://doi.org/10.1007/BF00957357

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