Reaction of diisobutylchlorophosphine with 1,1-dichloro-1-nitrosoalkanes in the presence of SO2 and ethyl mercaptan
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Diisobutylchlorophosphine reacts exothermally with 1,1-dichloro-1-nitrosoalkanes in the presence of SO2 to give O-alkylchloroformiminodiisobutylphosphinates, while in the presence of ethyl mercaptan this reaction gives O-alkylchloroformiminodiisobutylthiophosphinates.
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