Reaction of diisobutylchlorophosphine with 1,1-dichloro-1-nitrosoalkanes in the presence of SO2 and ethyl mercaptan

  • V. B. Sokolov
  • A. N. Ivanov
  • T. A. Epishina
  • I. V. Martynov
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Conclusions

Diisobutylchlorophosphine reacts exothermally with 1,1-dichloro-1-nitrosoalkanes in the presence of SO2 to give O-alkylchloroformiminodiisobutylphosphinates, while in the presence of ethyl mercaptan this reaction gives O-alkylchloroformiminodiisobutylthiophosphinates.

Literature cited

  1. 1.
    I. V. Martynov, Yu. L. Kruglyak, and N. F. Privezentseva, Proceedings of the 3rd Conference on the Chemistry and Applications of Organophosphorus Compounds [in Russian], Nauka, Moscow (1971).Google Scholar
  2. 2.
    G. M. Kosolapoff and L. Maier, Organic Phosphorus Compounds, Vol. 3 (1972), p. 219.Google Scholar

Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • V. B. Sokolov
    • 1
  • A. N. Ivanov
    • 1
  • T. A. Epishina
    • 1
  • I. V. Martynov
    • 1
  1. 1.Institute of Physiologically Active CompoundsAcademy of Sciences of the USSRChernogolovka

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