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Synthesis and19F-NMR spectra of fluoro-substituted dibenzenechromium derivatives

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Simultaneous condensation of chromium vapors with the vapors of two substituted benzenes, one of which was fluorobenzene, gives substituted dibenzenechromium complexes of the type (C6H5F)Cr(C6H5X).

  2. 2.

    The values of the19F chemical shifts correlate satisfactorily with the σm + and σm p substituent constants.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organometallic Chemistry, Academy of Sciences of the USSR, Moscow

    V. A. Sergeev, L. P. Yur'eva, A. S. Peregudov, A. Yu. Vasil'kov, I. A. Uralets, N. N. Zaitseva & D. N. Kravtsov

Authors
  1. V. A. Sergeev
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  2. L. P. Yur'eva
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  3. A. S. Peregudov
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  4. A. Yu. Vasil'kov
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  5. I. A. Uralets
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  6. N. N. Zaitseva
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  7. D. N. Kravtsov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2576–2579, November, 1987.

The authors thank N. I. Vasyukov for carrying out the mass spectrometric investigations.

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Sergeev, V.A., Yur'eva, L.P., Peregudov, A.S. et al. Synthesis and19F-NMR spectra of fluoro-substituted dibenzenechromium derivatives. Russ Chem Bull 36, 2391–2395 (1987). https://doi.org/10.1007/BF00957324

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  • DOI: https://doi.org/10.1007/BF00957324

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