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Reactions of polyfluorocarbonyl compounds with phenolates

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Hexafluoroacetone and methyl trifluoropyruvate react under mild conditions with sodium phenolate, sodium alkoxyphenolates, sodium alkylphenolates, and sodium dialkylphenolates to give the ortho-alkylation and ortho,ortho-dialkylation products. In the case of sodium phenolate, the tri-C-alkylation product is also obtained. The second C-alkylation of meta-substituted sodium phenolates was found to be difficult.

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Literature cited

  1. V. I. Dyachenko, A. F. Kolomets, and A. V. Fokin, Zh. Org. Khim.,23, 893 (1987).

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  2. V. I. Dyachenko, A. F. Kolomets, and A. V. Fokin, Izv. Akad. Nauk SSSR, Ser. Khim., 1080 (1987).

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. I. Dyachenko, A. F. Kolomets & A. V. Fokin

Authors
  1. V. I. Dyachenko
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  2. A. F. Kolomets
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  3. A. V. Fokin
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Additional information

For previous communication, see ref. [1].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2849–2852, December, 1987.

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Dyachenko, V.I., Kolomets, A.F. & Fokin, A.V. Reactions of polyfluorocarbonyl compounds with phenolates. Russ Chem Bull 36, 2646–2648 (1987). https://doi.org/10.1007/BF00957257

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  • DOI: https://doi.org/10.1007/BF00957257

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