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Chain termination in the telomerization of propylene with CCl4 initiated by tert-butyl peroxide and the W(CO)6-PPh3 system

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The use of PPh3 as a coinitiator in the telomerization of propylene with CCl4 leads to a significant increase in the yield of allylic termination products relative to initiation with TBP or W(CO)6.

  2. 2.

    Independently of the course of the telomerization, PPh3 reacts with propylene and CCI4, with the formation of CHCl3, i-PrCl, and n-PrCl.

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Literature cited

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    R. Kh. Freidlina, A. L. Tumanskaya, S. V. Vitt & N. A. Grigor'ev

Authors
  1. R. Kh. Freidlina
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  2. A. L. Tumanskaya
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  3. S. V. Vitt
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  4. N. A. Grigor'ev
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Additional information

Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2844–2847, December, 1987.

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Freidlina, R.K., Tumanskaya, A.L., Vitt, S.V. et al. Chain termination in the telomerization of propylene with CCl4 initiated by tert-butyl peroxide and the W(CO)6-PPh3 system. Russ Chem Bull 36, 2641–2643 (1987). https://doi.org/10.1007/BF00957255

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  • DOI: https://doi.org/10.1007/BF00957255

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