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Thermal decomposition of isomeric 3-nitro-4-phenylfuroxane and 4-nitro-3-phenylfuroxane in the gas phase

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The equal rates of gas-phase decomposition of 3-nitro-4-phenylfuroxane and 4-nitro-3-phenylfuroxane is a consequence of their rapid monomolecular isomerization.

  2. 2.

    Monomolecular decomposition of the heterocycle in 3-nitro-4-phenylfuroxane and 4-nitro-3-phenylfuroxane is facilitated due to the effect of the nitro and phenyl groups.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemical Physics, Chernogolovka Branch, Academy of Sciences of the USSR, USSR

    V. G. Prokudin, G. M. Nazin & I. V. Ovchinnikov

Authors
  1. V. G. Prokudin
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  2. G. M. Nazin
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  3. I. V. Ovchinnikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2841–2844, December, 1987.

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Prokudin, V.G., Nazin, G.M. & Ovchinnikov, I.V. Thermal decomposition of isomeric 3-nitro-4-phenylfuroxane and 4-nitro-3-phenylfuroxane in the gas phase. Russ Chem Bull 36, 2638–2640 (1987). https://doi.org/10.1007/BF00957254

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  • DOI: https://doi.org/10.1007/BF00957254

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