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Trifluoroacetylation of furan compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Furan, 2-alkylfurans, and 1,1-di(fur-2-yl)alkanes react with trifluoroacetic anhydride to giveα-trifluoroacetyl derivatives of furan.

  2. 2.

    In the case of 2,5-dimethylfuran, the trifluoroacetylation proceeds at the exposition of the furan ring and the methyl group to form a substituted 2,5-dihydrofuran.

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Literature cited

  1. N. V. Konstantinova, L. P. Kolobanova, E. V. Shchaveleva, et al., Zh. Vses. Khim. Obshch. im. D. I. Mendeleeva,26, 112 (1981).

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  3. V. I. Ivanskii, The Chemistry of Heterocyclic Compounds [in Russian], Izd. Vyssh. Shkola, Moscow (1978), p. 117.

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  4. V. M. Shostakovskii, M. Ya. Samoilova, and O. M. Nefedov, Izv. Akad. Nauk SSSR, Ser. Khim., 2382 (1973).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. G. Glukhovtsev, Yu. V. Il'in, A. V. Ignatenko & L. Yu. Brezhnev

Authors
  1. V. G. Glukhovtsev
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  2. Yu. V. Il'in
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  3. A. V. Ignatenko
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  4. L. Yu. Brezhnev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2834–2837, December, 1987.

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Glukhovtsev, V.G., Il'in, Y.V., Ignatenko, A.V. et al. Trifluoroacetylation of furan compounds. Russ Chem Bull 36, 2631–2633 (1987). https://doi.org/10.1007/BF00957251

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  • DOI: https://doi.org/10.1007/BF00957251

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