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Reaction of polyfluoroaromatics with o- and p- aminophenols in DMF

  • T. N. Gerasimova
  • E. F. Kolchina
  • I. Yu. Kargapolova
Organic Chemistry

Conclusions

  1. 1.

    The reaction of pentafluorobenzene with o- and p-aminophenols can lead to the corresponding hydroxydiarylamine (neutral medium) or to the aminodiphenyl ether (in the presence of base).

     
  2. 2.

    In contrast to 2,3,4,5,6-pentafluoro-2′-aminadiphenyl ether, 4-nitro-2,3,5,6-tetrafluoro-2′-aminodiphenyl ether rearranged to the isomeric 2-hydroxydiphenylamine.

     

Keywords

Ether Aminophenol Neutral Medium Pentafluorobenzene Aminodiphenyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • T. N. Gerasimova
    • 1
  • E. F. Kolchina
    • 1
  • I. Yu. Kargapolova
    • 1
  1. 1.Novosibirsk Institute of Organic Chemistry, Siberian BranchAcademy of Sciences of the USSRUSSR

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