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Participation of C4, and C5 dienes in the pyrolytic formation of aromatic hydrocarbons

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    It was established that in pyrolysis the precursors of benzene are the dienes piperylene and cyclopentadiene.

  2. 2.

    Based on the obtained data the assumption was made that formation of benzene proceeds by successive addition of methyl radicals to C4 and C5 dienes.

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Literature cited

  1. S. P. Gorislavets, D. N. Tmenov, and V. I. Maiorov, Pyrolysis of Hydrocarbon Raw Materials [in Russian], Nauk, Dumka, Kiev (1977).

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  2. G. V. Isagulyants, A. A. Greish, G. V. Kostina, and Yu. M. Zhorov, Izv. Akad. Nauk SSSR, Ser. Khim., 1340 (1984).

  3. G. V. Isagulyants, A. A. Treish, Yu. M. Zhorov, and G. V. Kostina, Izv. Akad. Nauk SSSR, Ser. Khim., 1556 (1984).

  4. R. Z. Magaril, Theoretical Bases of Chemical Processes in Crude Oil Refining [in Russian], Khimiya, Moscow (1976).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    G. V. Isagulyants, A. A. Greish, L. I. Kovalenko & G. V. Kostina

Authors
  1. G. V. Isagulyants
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  2. A. A. Greish
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  3. L. I. Kovalenko
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  4. G. V. Kostina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2783–2787, December, 1987.

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Isagulyants, G.V., Greish, A.A., Kovalenko, L.I. et al. Participation of C4, and C5 dienes in the pyrolytic formation of aromatic hydrocarbons. Russ Chem Bull 36, 2580–2583 (1987). https://doi.org/10.1007/BF00957238

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  • DOI: https://doi.org/10.1007/BF00957238

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