Skip to main content
SpringerLink
Log in

Increased resistance to mass transfer in capillary columns with unevenly coated stationary phases

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The main factor of additional zonal wash-out is the nonhomogeneous distribution of stationary phases leading to a strong increase in the resistance to mass transfer in the carrier gas. This wash-out factor can amount to 50% of the experimental value of HETP.

  2. 2.

    The diffusional resistance in droplets of nonpolar silicone phases augments the HETP value by not more than 10%.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. T. W. Smuts, T. S. Buys, T. G. du Toit, J. W. du Toit, and P. A. Torline, J. High Resolut. Chromatogr. and Chromatogr. Commun.,4, 385 (1981).

    Google Scholar 

  2. J. Krupčik, J. Garaj, P. Čellar, and G. Guiochon, J. Chromatogr.,312, 1 (1984).

    Google Scholar 

  3. V. G. Garbuzov, A. V, Vasil'ev, and R. V. Golovnya, Izv. Akad. Nauk SSSR, Ser. Khim., 611 (1982).

  4. J. Bouche and M. Verzele, J. Gas Chromatogr.,6, 501 (1968).

    Google Scholar 

  5. E. L. Ilkova and E. A. Mistryukov, J. Chromatogr. Sci.,9, 569 (1971).

    Google Scholar 

  6. L. S. Ettre, Gas Chromatography, Littlewood A. B., London, Institute of Petroleum, (1967), p. 115.

  7. W. Millen and S. Hawkes, J. Chromatogr. Sci.,15, 148 (1977).

    Google Scholar 

  8. G. Redant, P. Sandra, and M. Verzele, Chromatographia,15, 13 (1982).

    Google Scholar 

  9. L. G. Blomberg, J. High Resolut. Chromatogr. and Chromatogr. Commun.,7, 232 (1984).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organometallic Compounds, Academy of Sciences of the USSR, Moscow

    A. V. Vasil'ev & R. B. Golovnya

Authors
  1. A. V. Vasil'ev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. B. Golovnya
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2760–2764, December, 1987.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vasil'ev, A.V., Golovnya, R.B. Increased resistance to mass transfer in capillary columns with unevenly coated stationary phases. Russ Chem Bull 36, 2557–2561 (1987). https://doi.org/10.1007/BF00957234

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00957234

Keywords

Search

Navigation