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Phosphorus crowns. Communication 8. The molecular structure and complexation properties of phenylphosphonyldibenzo-17-crown-6

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The stability constants were determined for the complexes of 17-membered phosphorus-containing crown ethers in the series of Li, Na, K, Ca, and Mg picrates in methylene chloride and the size of the macrocyclic ring was found to have a significant effect on the complexing capacity of phosphorus polyethers.

  2. 2.

    An x-ray diffraction structural analysis showed that the replacement of an adamantyl group by a phenyl substituent did not lead to a rearrangement of the macrocycle such that the phosphoryl oxygen atom could participate in coordination simultaneously with the anisole and ether oxygen atoms.

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Authors and Affiliations

  1. Institute of Chemical Physics, Chernogolovka Branch, Academy of Sciences of the USSR, Kiev

    V. V. Tkachev, A. A. Chaikovskaya, L. O. Atovmyan, G. V. Sazonova & T. N. Kudrya

  2. Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev

    V. V. Tkachev, A. A. Chaikovskaya, L. O. Atovmyan, G. V. Sazonova & T. N. Kudrya

Authors
  1. V. V. Tkachev
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  2. A. A. Chaikovskaya
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  3. L. O. Atovmyan
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  4. G. V. Sazonova
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  5. T. N. Kudrya
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Additional information

For communication 7, see ref. [1].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2745–2750, December, 1987.

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Tkachev, V.V., Chaikovskaya, A.A., Atovmyan, L.O. et al. Phosphorus crowns. Communication 8. The molecular structure and complexation properties of phenylphosphonyldibenzo-17-crown-6. Russ Chem Bull 36, 2544–2548 (1987). https://doi.org/10.1007/BF00957230

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  • DOI: https://doi.org/10.1007/BF00957230

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