Conclusions
X-ray diffraction structural data, a PPP quantum chemical calculation, and IR and UV spectral indices indicate that there is a six-membered chelate formazyl group with syn, s-cis configuration and strong intramolecular hydrogen bonding is characteristic for 1-p-anisyl-3,5-diphenylformazane. Spectroscopic criteria were established for this configuration of the formazane molecule.
Similar content being viewed by others
Literature cited
V. A. Kosobutskii, Chemical Sciences Candidate's Dissertation, Vladimir (1972).
M. Dewar, Molecular Orbital Theory of Organic Chemistry, McGraw-Hill, New York (1969).
Yu. V. Zefirov and P. M. Zorkii, Zh. Strukt. Khim.,17, 1966 (1976).
T. S. Kolodina, Chemical Sciences Candidate's Dissertation, Moscow (1983).
I. W. Le Fever, I. B. Souse, and R. L. Werner, Austr. J. Chem., 151 (1956).
G. Arnold and C. Schiele, Spectrochim. Acta,25A, 685 (1969).
I. I. Kukushkina, Chemical Sciences Candidate's Dissertation, Rostov-on-the-Don (1972).
Kh. M. Severo, Chemical Sciences Candidate's Dissertation, Moscow (1984).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2739–2745, December, 1987.
Rights and permissions
About this article
Cite this article
Sokol, V.I., Davydov, V.V., Porai-Koshits, M.A. et al. X-ray diffraction structural and spectrochemical study of 1-p-anisyl-3-5,diphenylformazane. Russ Chem Bull 36, 2539–2543 (1987). https://doi.org/10.1007/BF00957229
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00957229