Conclusions
Using the PMR method we have shown that aromatic nitro compounds form outer-sphere do-nor-acceptor adducts with the alizarin complex of Mn(II), which is the structural analog of metal complex catalysts for hydration of aromatic nitro compounds.
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Literature cited
A. V. Bulatov, A. T. Nikitaev, and M. L. Khidekel', Advances in the Chemistry of Charge Transfer Complexes and Radical-Ion Salts [in Russian], Chernogolovka (1986), p. 187.
M. L. Khidekel and A. V. Bulatov, Proceedings, 2nd International Summer School on Metal Complex Catalysis GDR, Noubrandenburg (1984), p. 125.
A. V. Bulatov and M. L. Khidekel, Trans. Metal. Chem.,5, 123 (1980).
A. V. Bulatov, M. L. Khidekel, A. N. Egorochkin, et al., Trans. Met. Chem.,8, 289 (1983).
A. N. Kitaigorodskii, V. M. Nekipelov, and K. I. Zamaraev, Zh. Strukt. Khim.,19, 796 (1978).
D. M. Doddrell, D. T. Pegg, R. Bendal, and A. K. Gregson, Chem. Phys. Lett.,40, 142 (1976).
D. R. Eaton, Can. J. Chem.,47, 2645 (1969).
H. Grahn, U. Edlund, and G. C. Levy, J. Magn. Reson.,56, 61 (1984).
R. Foster, Organic Charge-Transfer Complexes, Academic Press, New York (1969).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2715–2719, December, 1987.
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Kitaigorodskii, A.N., Bulatov, A.V. NMR study of adducts of aromatic nitro compounds with the alizarin complex of manganese(II) — A structural analog of hydration catalysts. Russ Chem Bull 36, 2517–2520 (1987). https://doi.org/10.1007/BF00957224
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DOI: https://doi.org/10.1007/BF00957224