Conclusions
The behavior of acetates of glycofuranosyl fluorides under protolysis conditions in the gaseous phase is mainly determined by the relative configurations of the substituents at C1 and C4 atoms: the cis isomers form the [MH-HF]+ ions with higher probability, and the trans isomers, the [MH-AcOH]+ ions.
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V. I. Kadentsev, I. A. Trushkina, O. S. Chizhov, and Ya. V. Voznyi, Izv. Akad. Nauk SSSR, Ser. Khim., 2580 (1987).
Ya. V. Voznyi, I. S. Kalicheva, and A. A. Galoyan, Bioorg. Khim.,7, 406 (1981).
A. A. Solov'ev, V. I. Kadentsev, and O. S. Chizhov, Izv. Akad. Nauk SSSR, Ser. Khim., 2256 (1976).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2708–2711, December, 1987.
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Kadentsev, V.I., Trushkina, I.A., Chizhov, O.S. et al. Behavior of acetates of furanosyl fluorides under protolysis conditions in gaseous phase. Russ Chem Bull 36, 2510–2512 (1987). https://doi.org/10.1007/BF00957222
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DOI: https://doi.org/10.1007/BF00957222