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Fragmentation pathways of [(Ph3P)AuM(CO)3(n5-C5H4CHO)] upon electron impact in the gas phase or upon photolysis in solution

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

In heterobimetallic complexes of the type (η5-formylcyclopentadienyl)(triphenylphosphine-gold)tricarbonylchromium (molybdenum, tungsten) the Au-transition metal bond is easily cleaved either in the gas phase via electron impact (ionization), or in the liquid phase by photolysis.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organometallic Chemistry, Academy of Sciences of the USSR, Moscow

    N. I. Vasyukova, B. L. Tumanskii, B. N. Strunin, K. I. Grandberg, Yu. S. Nekrasov, N. N. Bubnov, S. P. Solodovnikov & A. I. Prokof'ev

Authors
  1. N. I. Vasyukova
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  2. B. L. Tumanskii
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  3. B. N. Strunin
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  4. K. I. Grandberg
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  5. Yu. S. Nekrasov
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  6. N. N. Bubnov
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  7. S. P. Solodovnikov
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  8. A. I. Prokof'ev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2702–2708, December, 1987.

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Vasyukova, N.I., Tumanskii, B.L., Strunin, B.N. et al. Fragmentation pathways of [(Ph3P)AuM(CO)3(n5-C5H4CHO)] upon electron impact in the gas phase or upon photolysis in solution. Russ Chem Bull 36, 2504–2509 (1987). https://doi.org/10.1007/BF00957221

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  • DOI: https://doi.org/10.1007/BF00957221

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