Some transformations of fluorochloronitroalcohols

  • V. K. Brel'
  • L. A. Chepakova
  • N. F. Kartavtseva
  • I. V. Martynov
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Conclusions

Previously unreported bis(fluorochloronitroalkyl) sulfites were obtained upon carrying out the reactions with flushing of hydrogen chloride by an inert gas or using an amine acceptor, while the reaction with SOCl2+DMF (the Weismeier-Haake reagent) gives O-formylation. Fluorochloronitromethyl ketones were obtained for the first time upon the oxidation of secondary fluorochloronitroalcohols using potassium dichromate.

Keywords

Oxidation Hydrogen Chloride Potassium Ketone 

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Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • V. K. Brel'
    • 1
  • L. A. Chepakova
    • 1
  • N. F. Kartavtseva
    • 1
  • I. V. Martynov
    • 1
  1. 1.Institute of Physiologically Active CompoundsAcademy of Sciences of the USSRChernogolovka

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