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Reaction of the N, N-dimethylamide and methyl ester of 3-phenyl-3-chloro-2-ketopropionic acid with triphenylphosphine

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The dimethylamide of 3-phenyl-3-chloro-2-ketopropionic acid reacts with Ph3P to give α-(N,N-dimethyloxamoyl)benzyltriphenylphosphonium chloride. In the presence of methanol, this reaction gives dimethyl(phenylpyruvoyl)amide and Ph3PO.

2. The methyl ester of 3-phenyl-3-chloro-2-ketopropionic acid reacts with Ph3P to give methoxycarbonylstyryloxytriphenylphosphonium chloride, which, upon heating in benzene at reflux, gives methyl α-chlorocinnamate and Ph3PO.

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Literature cited

  1. A. J. Kirby and S. G. Warren, The Organic Chemistry of Phosphorus, Elsevier, New York (1967).

    Google Scholar 

  2. I. J. Borowitz, K. C. Kirby, P. E. Rusek, and E. W. R. Casper, J. Org. Chem.,36, 88 (1971).

    Google Scholar 

  3. V. A. Mamedov, I. A. Nuretdinov, and F. G. Sibgatullina, Izv. Akad. Nauk SSSR, Ser. Khim., No. 10, 2172 (1988).

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  4. J. M. Samrier, R. Danion-Bouget, D. Danion, and R. Carrie, Bull. Soc. Chim., France, 3227 (1976).

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR

    V. A. Mamedov, I. A. Nuretdinov & V. L. Polushina

Authors
  1. V. A. Mamedov
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  2. I. A. Nuretdinov
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  3. V. L. Polushina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1395–1396, June, 1989.

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Mamedov, V.A., Nuretdinov, I.A. & Polushina, V.L. Reaction of the N, N-dimethylamide and methyl ester of 3-phenyl-3-chloro-2-ketopropionic acid with triphenylphosphine. Russ Chem Bull 38, 1276–1277 (1989). https://doi.org/10.1007/BF00957170

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  • DOI: https://doi.org/10.1007/BF00957170

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