Skip to main content
SpringerLink
Log in

Three-dimensional structures of phosphorus-containing heterocycles 50. 2-dimethylamino-2-oxo- and -2-thiono-1,3,2-oxathiaphosphorinanes

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A chair conformation with an axial orientation of the phosphoryl or thiophosphoryl group is preferable for 2-dimethylamino-2-oxo- and-2-thiono-1,3,2-oxathiaphosphorinanes. The cis isomer of 2-dimethylamino-2-oxo-4-methyl-1,3,2-oxathiaphosphorinane has a similar structure with an equatorial orientation of the 4-methyl group, while the corresponding sulfide is characterized by a trans configuration with a reoriented positioning of the substituents attached to the phosphorus atom.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. B. A. Arbuzov, R. P. Arshinova, and N. A. Polezhaeva, Izv. Akad. Nauk SSSR, Ser. Khim., No. 11, 2507 (1983).

    Google Scholar 

  2. B. A. Arbuzov, R. P. Arshinova, O. V. Ovodova, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 3, 570 (1985).

    Google Scholar 

  3. R. R. Shagidullin, I. Kh. Shakirov, A. Kh. Plyamovatyi, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 11, 2517 (1984).

    Google Scholar 

  4. A. Kh. Plyamovatyi, R. R. Shagidullin, I. Kh. Shakirov, and R. P. Arshinova, Izv. Akad. Nauk SSSR, Ser. Khim., No. 1, 92 (1987).

    Google Scholar 

  5. B. A. Arbuzov, R. P. Arshinova, V. N. Nabiullin, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 4, 796 (1983).

    Google Scholar 

  6. R. P. Arshinova, S. G. Gnevashev, R. A. Kadyrov, et al., Zh. Obshch. Khim.,58, No. 11, 2417 (1988).

    Google Scholar 

  7. O. N. Nuretdinova and F. F. Guseva, Izv. Akad. Nauk SSSR, Ser. Khim., No. 9, 2136 (1984).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. M. Butlerov Chemical Institute, V. I. Ul'yanov-Lenin Kazan State University, USSR

    B. A. Arbuzov, R. P. Arshinova, O. A. Bulgakova, O. N. Nuretdinova, F. F. Guseva, I. Kh. Shakirov, Sh. K. Latynov & A. V. Il'yasov

Authors
  1. B. A. Arbuzov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. P. Arshinova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. A. Bulgakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. N. Nuretdinova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. F. F. Guseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. I. Kh. Shakirov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Sh. K. Latynov
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. A. V. Il'yasov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1369–1374, June, 1989.

The authors thank I. A. Litvinov and V. A. Naumov for carrying out the x-ray diffraction analysis.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Arbuzov, B.A., Arshinova, R.P., Bulgakova, O.A. et al. Three-dimensional structures of phosphorus-containing heterocycles 50. 2-dimethylamino-2-oxo- and -2-thiono-1,3,2-oxathiaphosphorinanes. Russ Chem Bull 38, 1251–1256 (1989). https://doi.org/10.1007/BF00957163

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00957163

Keywords

Search

Navigation