Conclusions
Molecules of aromatic nitrocompounds are shown to be located directly over the metal ion in molecular complexes which are formed in chloroform with meso-tetraphenylporphinatoiron (III) chloride using1H and13C NMR methods. The stability constants of the corresponding adducts are similar in the case of meso-tetraphenylporphinates of Fe(III) and Co(II).
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O. A. Chamaeva and A. N. Kitaigorodskii, Izv. Akad. Nauk SSSR, Ser. Khim., No. 6, 1263 (1989).
R. V. Snyder and G. N. La Mar, J. Am. Chem. Soc.,99, 7178 (1977).
A. T. Kabbani and G. N. La Mar, J. Magn. Reson.,43, 90 (1981).
R. A. Abraham, G. R. Bedford, D. McNeillie, and B. Wright, Org. Magn. Reson.,14, 418 (1980).
G. N. Le Mar and F. A. Walker, The Porphyrins, Vol. 4, D. Dolphin (ed.), Academic Press, N. Y. (1979), p. 61.
A. N. Kitaigorodskii and A. V. Kessenikh, Zh. Fiz. Khim.,59, 2657 (1985).
A. N. Kitaigorodskii, V. M. Nekipelov, and K. I. Zamaraev, Zh. Strukt. khim.,19, 796 (1978).
G. P. Fulton and G. N. Le Mar, J. Am. Chem. Soc.,98, 2124 (1976).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1269–1273, June, 1989.
The authors thank A. B. Solov'ev and A. V. Bulatov for supplying the TPPFeCl and ANC, and A. G. Stepanov for recording the13C NMR spectra.
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Chamaeva, O.A., Kitaigorodskii, A.N. Unusual structure of molecular complexes of metal tetraarylporphinates with simple aromatic π-acceptors 2. Tetraphenylporphinatoiron(III) chloride. Russ Chem Bull 38, 1155–1158 (1989). https://doi.org/10.1007/BF00957144
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DOI: https://doi.org/10.1007/BF00957144