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Unusual structure of molecular complexes of metal tetraarylporphinates with simple aromatic π-acceptors 1. Tetraphenylporphinatocobalt(II)

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

1H NMR was used to show that aromatic nitrocompound (ANC) molecules are located not on the periphery of porphyrin in molecular complexes which are formed between meso-tetraphenylporphinatocobalt (II) and ANC in chloroform solutions, as was assumed earlier, but directly over the metal ion. The stability of the molecular complexes increases substantially with increasing number of nitro groups in the ANC.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    O. A. Chamaeva & A. N. Kitaigorodskii

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  1. O. A. Chamaeva
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  2. A. N. Kitaigorodskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1263–1269, June, 1989.

The authors thank A. B. Solov'ev and A. V. Bulatov for supplying CoTPP and ANC.

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Chamaeva, O.A., Kitaigorodskii, A.N. Unusual structure of molecular complexes of metal tetraarylporphinates with simple aromatic π-acceptors 1. Tetraphenylporphinatocobalt(II). Russ Chem Bull 38, 1150–1155 (1989). https://doi.org/10.1007/BF00957143

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  • DOI: https://doi.org/10.1007/BF00957143

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