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Influence of the solvent on the activation parameters of the conformational conversions of 2-substituted 1, 3-dithia-5,6-benzocycloheptenes

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The enthalpy and entropy of activation of the chair(e)-boat(e) interconversion for 2-substituted 1,3-dithia-5,6-benzocycloheptenes depend significantly on the type of the solvent, whereby the changes in the enthalpy of equilibrium and of activation are not determined by the same factors when the solvent is changed.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR

    Sh. K. Latypov, V. V. Klochkov, A. V. Aganov, A. V. Il'yasov & B. A. Arbuzov

  2. V. I. Ul'yanov-Lenin Kazan State University, USSR

    Sh. K. Latypov, V. V. Klochkov, A. V. Aganov, A. V. Il'yasov & B. A. Arbuzov

Authors
  1. Sh. K. Latypov
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  2. V. V. Klochkov
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  3. A. V. Aganov
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  4. A. V. Il'yasov
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  5. B. A. Arbuzov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1253–1256, June, 1989.

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Latypov, S.K., Klochkov, V.V., Aganov, A.V. et al. Influence of the solvent on the activation parameters of the conformational conversions of 2-substituted 1, 3-dithia-5,6-benzocycloheptenes. Russ Chem Bull 38, 1139–1142 (1989). https://doi.org/10.1007/BF00957140

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  • DOI: https://doi.org/10.1007/BF00957140

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