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Esterification of phthalic anhydride by alcohols in the presence of titanium bis(β-diketonates)

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

In the esterification of phthalic anhydride by 2-ethylhexanol in the presence of titanium bis(β-diketonates), the rate constants of the reaction increase with decreasing stability of the chelate. The relation of the rate constant of the reaction of phthalic anhydride with normal C6-C9 alcohols catalyzed by bis (acetylacetonato) dibutoxytitanium and butyl orthotitanate in a medium of the corresponding diesters is extremal in nature because of the different degree of hydrolysis of the catalyst during esterification.

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Authors and Affiliations

  1. Institute of Chemistry, Ural Branch, Academy of Sciences of the USSR, Sverdlovsk

    E. A. Khrustaleva, Yu. G. Yatluk & A. L. Suvorov

Authors
  1. E. A. Khrustaleva
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  2. Yu. G. Yatluk
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  3. A. L. Suvorov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1247–1250, June, 1989.

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Khrustaleva, E.A., Yatluk, Y.G. & Suvorov, A.L. Esterification of phthalic anhydride by alcohols in the presence of titanium bis(β-diketonates). Russ Chem Bull 38, 1133–1136 (1989). https://doi.org/10.1007/BF00957138

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  • DOI: https://doi.org/10.1007/BF00957138

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