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Alkenyl carbenium ions on HTsVK zeolites

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The formation of alkenyl carbocations from propylene,1,3-butadiene, and methanol on HTsVK zeolites was followed; they decompose at 513–573 K.

  2. 2.

    Alkenyl carbocations are characterized by νas CCC at 1500–1530 cm−1 in the IR spectra (30 cm−1 isotope shift) and bands in the DRS at: 290–310, 350–380, 430–450, and 520–570 nm.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1229–1233, June, 1989.

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Demidov, A.V., Davydov, A.A. & Kurina, L.N. Alkenyl carbenium ions on HTsVK zeolites. Russ Chem Bull 38, 1117–1121 (1989). https://doi.org/10.1007/BF00957134

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  • DOI: https://doi.org/10.1007/BF00957134

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