Conclusions
-
1.
The formation of alkenyl carbocations from propylene,1,3-butadiene, and methanol on HTsVK zeolites was followed; they decompose at 513–573 K.
-
2.
Alkenyl carbocations are characterized by νas CCC at 1500–1530 cm−1 in the IR spectra (30 cm−1 isotope shift) and bands in the DRS at: 290–310, 350–380, 430–450, and 520–570 nm.
Similar content being viewed by others
Literature cited
H. P. Leftin and M. S. Hobson, Catalysis. Physical Chemistry of Heterogeneous Catalysis [Russian translation], Mir, Moscow (1967), p. 7.
V. Bolis, J. C. Vedrine, J. P. Van de Berg, et al., J. Chem. Soc. Faraday Trans. 1,76, No. 7, 1606 (1980).
J. Novakova, L. Kubelkova, Z. Dolejsek, and P. Jiru, Collect. Czech. Chem. Commun.,44, No. 11, 3341 (1979).
V. B. Kazanskii, Kinet. Katal.,28, No. 1, 47 (1987).
J. C. Vedrine, P. Dejaife, E. D. Garbovski, and E. G. Derouane, in: Proceedings of the International Symposium on Catalysis by Zeolites, B. Imelik et al. (eds.), Elsevier, Amsterdam (1980), p. 29.
B. Kontnik-Mattecka, M. Gorska, J. Eysymontt, and A. Salek, J. Mol. Struct.,80, 199 (1982).
H. Lechert, C. Dimitrov, C. Bezuhanova, and V. Nenova, J. Gatai.,80, No. 2, 457. (1983).
H. Förster, and J. Seebode, Proceedings of the International Symposium on Zeolite Catalysis, Siofok, Hungary (1985), p. 413.
N. S. Deno, Current Problems in Physical Organic Chemistry [Russian translation], Mir, Moscow (1967), p. 393.
T. S. Sorensen, J. Am. Chem. Soc.,87, No. 22, 5075 (1965).
L. J. Bellamy, The Infrared Spectra of Complex Molecules, Methuen, London (1958).
P. Fejes, H. Förster, I. Kiricsi, and J. Seebode, in: Proceedings of the International Conference in Studies in Surface Science and Catalysis. 18. Structure and Reactivity of Modified Zeolites, P. A. Jacobs et al. (eds.), Elsevier, Amsterdam (1984), p. 91.
J. E. Germain, Catalytic Conversion of Hydrocarbons, Academic Press, New York (1969).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1229–1233, June, 1989.
Rights and permissions
About this article
Cite this article
Demidov, A.V., Davydov, A.A. & Kurina, L.N. Alkenyl carbenium ions on HTsVK zeolites. Russ Chem Bull 38, 1117–1121 (1989). https://doi.org/10.1007/BF00957134
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00957134