Skip to main content
SpringerLink
Log in

Reaction of methylmagnesium iodide with perfluorocarboxylate esters

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

In the reaction of methylmagnesium iodide with esters of perfluorocarboxylic acids, the magnesium salt of the hemiketal was found to be more stable and the ketone yield was found to be higher with increasing bulk of the alkoxy group of the ester.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. L. S. Chen, G. J. Chen, and C. Tamborski, J. Fluorine Chem.,18, 117 (1981).

    Google Scholar 

  2. L. S. Chen and C. Tamborski, J. Fluorine Chem.,19, A3 (1981/1982).

    Google Scholar 

  3. L. P. Shadrina, Yu. P. Dormidontov, and A. N. Nedugov, Zh. Org. Khim.,8, 1609 (1981).

    Google Scholar 

  4. L. S. Chen and C. Tamborski, J. Fluorine Chem.,26, 269 (1984).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    D. V. Batizat, A. A. Yarosh, A. V. Ignatenko & V. A. Ponomarenko

Authors
  1. D. V. Batizat
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Yarosh
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Ignatenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. A. Ponomarenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1163–1165, May, 1988.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Batizat, D.V., Yarosh, A.A., Ignatenko, A.V. et al. Reaction of methylmagnesium iodide with perfluorocarboxylate esters. Russ Chem Bull 37, 1022–1024 (1988). https://doi.org/10.1007/BF00957085

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00957085

Keywords

Search

Navigation