Skip to main content
SpringerLink
Log in

Electrochemical dimerization of 2-acetylthiophene

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The yield of 2,3-di-(2′-thienyl)-2,3-butanediol which is formed upon electroreduction of 2-acetylthiophene in DMF solution depends on the composition of the background electrolyte; the yield is at its maximum when the electrolysis is carried out in the presence of lithium salt.

  2. 2.

    Products resulting from subsequent reactions of non-pinacol-type dimeric dianions upon electrolysis of 2-acetylthiophene under an Ar atmosphere or CO2 were also isolated and characterized.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. P. Foulatier, J.-P. Salaun, and C. Caullet, C. r. Acad. Sci.,C279, 779 (1974).

    Google Scholar 

  2. P. Foulatier and C. Caullet, C. r. Acad. Sci.,C279, 25 (1974).

    Google Scholar 

  3. E. V. Kryukova and A. P. Tomilov, Electrokhimiya,5, 869 (1969).

    Google Scholar 

  4. V. P. Gul'tyai, L. M. Korotaeva, A. S. Mendkovich, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 834 (1981).

  5. V. P. Gul'tyai and L. M. Korotaeva, Izv. Akad. Nauk SSSR, Ser. Khim., 165 (1982).

  6. L. N. Vykhodtseva, L. N. Nekrasov, and S. I. Shoshkina, Electrokhimiya,15, 741 (1979).

    Google Scholar 

  7. L. N. Nekrasov, L. M. Vykhodseva, L. M. Korotayeva, and V. P. Gultyai, J. Electroanal. Chem.,138, 177 (1982).

    Google Scholar 

  8. V. P. Gul'tyai, L. M. Korotaeva, A. P. Rodionov, and A. M. Moiseenkov, Izv. Akad. Nauk SSSR, Ser. Khim., 1150 (1981).

  9. M. Hebert and C. Caullet, C. r. Acad. Sci.,C273, 825 (1971).

    Google Scholar 

  10. V. F. Lavrushin, S. V. Tsukerman, and V. M. Nikitchenko, Zh. Org. Khim.,32, 2677 (1962).

    Google Scholar 

  11. L. M. Korotaeva, T. Ya. Rubinskaya, M. Ya. Botnikov, and V. P. Gul'tyai, Izv. Akad. Nauk SSSR, Ser. Khim., 637 (1988).

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. P. Gul'tyai, L. M. Korotaeva & T. Ya. Rubinskaya

Authors
  1. V. P. Gul'tyai
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. M. Korotaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. Ya. Rubinskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1121–1125, May, 1988.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gul'tyai, V.P., Korotaeva, L.M. & Rubinskaya, T.Y. Electrochemical dimerization of 2-acetylthiophene. Russ Chem Bull 37, 983–987 (1988). https://doi.org/10.1007/BF00957073

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00957073

Keywords

Search

Navigation