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Polysulfonylethenes. 4. Reactions of E-1,2-di(organylsulfonyl)dichloroethenes with amines

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Reaction of 1,2-di(organylsulfonyl)dichloroethenes with primary amines results in quantitative yields of products with geminal sulfonyl groups, namely N,N-aminals of di(organylsulfonyl)ketenes.

  2. 2.

    In reaction of E-1,2-di(organylsulfonyl)dichloroethenes with secondary amines only products with one chlorine atom replaced by an amino group are formed and during reaction they partially hydrolyze.

  3. 3.

    A mechanism based on reaction of RSO2 − anion with the starting sulfone giving trisulfonylchloroethene as an intermediate was proposed.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    N. E. Dontsova, N. P. Petukhova, E. N. Prilezhaeva & V. S. Bogdanov

Authors
  1. N. E. Dontsova
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  2. N. P. Petukhova
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  3. E. N. Prilezhaeva
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  4. V. S. Bogdanov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1104–1110, May, 1988.

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Dontsova, N.E., Petukhova, N.P., Prilezhaeva, E.N. et al. Polysulfonylethenes. 4. Reactions of E-1,2-di(organylsulfonyl)dichloroethenes with amines. Russ Chem Bull 37, 966–971 (1988). https://doi.org/10.1007/BF00957071

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  • DOI: https://doi.org/10.1007/BF00957071

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