Skip to main content
SpringerLink
Log in

Hydrogen bonds involving CO bridging groups in cyclopentadienyl iron dicarbonyl dimer

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Using the example of the complex [η5-C5H5Fe(CO)2]2, it has been shown that the bridging carbonyl groups are able to form hydrogen bonds with donor protons.

  2. 2.

    Protonation of the complex [η5-C5H5Fe(CO)2]2 has been detected in its reaction with perfluoro-tert-butanol and with HCl at the metal-metal bond in solution in liquid xenon.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. B. V. Lokshin, S. G. Kazaryan, and A. G. Ginzburg, Izv. Akad. Nauk SSSR, Ser. Khim., 2605 (1986).

  2. B. V. Lokshin, S. G. Kazaryan, and A. G. Ginzburg, Izv. Akad. Nauk SSSR, Ser. Khim., 562 (1988)

  3. B. V. Lokshin, A. G. Ginzburg, and E. B. Nazarova, Usp. Khim.,49, 223 (1980).

    Google Scholar 

  4. P. McArdle and A. R. Manning, J. Chem. Soc., (A), 2133 (1970).

  5. V. V. Bertsev, M. O. Bulanin, L. A. Zhigula, and T. D. Kolomiitsova, Molecular Spectroscopy [in Russian], Collection 2, Leningrad State University, Leningrad (1973), p. 81.

    Google Scholar 

  6. S. G. Kazaryan, B. V. Lokshin, Ya. M. Kimel'fel'd, and R. B. Materikova, Izv. Akad. Nauk SSSR, Ser. Khim., 2603 (1986).

  7. T. S. Piper, F. A. Cotton, and G. Wilkinson, J. Inorg. Nucl. Chem.,1, 165 (1955).

    Google Scholar 

  8. R. D. Fischer, A. Vogler, and K. Noack, J. Organomet. Chem.,7, 135 (1967).

    Google Scholar 

  9. J. G. Bullitt, F. A. Cotton, and T. J. Marks, Inorg. Chem.,11, 671 (1972).

    Google Scholar 

  10. D. F. Shriver, J. Organomet. Chem.,94, 259 (1975).

    Google Scholar 

  11. A. Davidson, W. McFarlane, L. Pratt, and G. Wilkinson, J. Chem. Soc., 3653 (1962).

  12. D. A. Symon and T. C. Waddington, J. Chem. Soc. (A), 953 (1971).

  13. D. C. Harris and H. B. Gray, Inorg. Chem.,14, 1215 (1975).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organometallic Compounds, Academy of Sciences of the USSR, Moscow

    B. V. Lokshin & S. G. Kazaryan

Authors
  1. B. V. Lokshin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. G. Kazaryan
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1074–1078, May, 1988.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lokshin, B.V., Kazaryan, S.G. Hydrogen bonds involving CO bridging groups in cyclopentadienyl iron dicarbonyl dimer. Russ Chem Bull 37, 939–942 (1988). https://doi.org/10.1007/BF00957065

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00957065

Keywords

Search

Navigation