Conclusions
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1.
Using thermometric titration and IR spectroscopy, we investigated the reaction of carbamoylmethylphosphoryl compounds (CMP) and of some monophosphoryl compounds with HNO3 in dichloroethane and in CCl4.
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2.
The interaction between CMP and HNO3 takes place in two stages with sharply different ΔH values which correspond to the formation of molecular complexes at the P=O and C=O groups.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1070–1074, May, 1988.
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Matrosov, E.I., Nesterova, N.P., Zarubin, A.I. et al. Reaction of carbamoylmethylphosphoryl compounds with nitric acid. Russ Chem Bull 37, 935–939 (1988). https://doi.org/10.1007/BF00957064
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DOI: https://doi.org/10.1007/BF00957064