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Magnetooptical properties in the anilinium series using Cotton-Mouton effect data

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    From the refractometry, static magnetochemistry and magnetic birefringence, data (the Cotton-Mouton effect) the different effect of ammonium and trimethyl ammonium substituents on the polarizability and magnetic susceptibility of the aromatic ring was established.

  2. 2.

    In primary anilinium salts the action of the positive charge is not large and amounts to some isotropic compression of the electron shell. The positive charge of the corresponding quaternary salts induces depression both of the total and of the anisotropic magnetooptical properties.

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Authors and Affiliations

  1. A. E. Arbuzov Organic and Physical Chemistry Institute, Kazan Branch, USSR Academy of Sciences, USSR

    A. P. Timosheva, S. G. Vul'fson, I. A. Kushnikovskii & A. N. Vereshchagin

Authors
  1. A. P. Timosheva
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  2. S. G. Vul'fson
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  3. I. A. Kushnikovskii
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  4. A. N. Vereshchagin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1061–1066, May, 1988.

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Timosheva, A.P., Vul'fson, S.G., Kushnikovskii, I.A. et al. Magnetooptical properties in the anilinium series using Cotton-Mouton effect data. Russ Chem Bull 37, 926–931 (1988). https://doi.org/10.1007/BF00957062

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  • DOI: https://doi.org/10.1007/BF00957062

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