Prototropic mechanism of intramolecular migration of the unpaired electron in the radical-cation of 3,6-di-tert-butylpyrocatechol orthocarbonate

  • N. A. Malysheva
  • A. I. Prokof'ev
  • T. I. Prokof'eva
  • N. N. Bubnov
  • S. P. Solodovnikov
  • M. I. Kabachnik
Physical Chemistry

Conclusion

The radical-cation of 3,6-di-tert-butylpyrocatechol orthocarbonate was obtained. It was established that the dynamic effects in its EPR spectra are due to the migration of a proton, attached by a hydrogen bond, from ligand to ligand.

Keywords

Hydrogen Migration Hydrogen Bond Dynamic Effect Unpaired Electron 

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Literature cited

  1. 1.
    N. A. Malysheva, A. I. Prokof'ev, N. N. Bubnov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1040 (1988).Google Scholar
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    V. B. Vol'eva, I. A. Novikova, I. S. Belostotskaya, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 2128 (1981).Google Scholar
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    V. B. Vol'eva, T. I. Prokof'eva, N. A. Novikova, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1632 (1984).Google Scholar

Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • N. A. Malysheva
    • 1
  • A. I. Prokof'ev
    • 1
  • T. I. Prokof'eva
    • 1
  • N. N. Bubnov
    • 1
  • S. P. Solodovnikov
    • 1
  • M. I. Kabachnik
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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