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Prototropic mechanism of intramolecular migration of the unpaired electron in the radical-cation of 3,6-di-tert-butylpyrocatechol orthocarbonate

  • N. A. Malysheva
  • A. I. Prokof'ev
  • T. I. Prokof'eva
  • N. N. Bubnov
  • S. P. Solodovnikov
  • M. I. Kabachnik
Physical Chemistry

Conclusion

The radical-cation of 3,6-di-tert-butylpyrocatechol orthocarbonate was obtained. It was established that the dynamic effects in its EPR spectra are due to the migration of a proton, attached by a hydrogen bond, from ligand to ligand.

Keywords

Hydrogen Migration Hydrogen Bond Dynamic Effect Unpaired Electron 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    N. A. Malysheva, A. I. Prokof'ev, N. N. Bubnov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1040 (1988).Google Scholar
  2. 2.
    V. B. Vol'eva, I. A. Novikova, I. S. Belostotskaya, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 2128 (1981).Google Scholar
  3. 3.
    V. B. Vol'eva, T. I. Prokof'eva, N. A. Novikova, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1632 (1984).Google Scholar

Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • N. A. Malysheva
    • 1
  • A. I. Prokof'ev
    • 1
  • T. I. Prokof'eva
    • 1
  • N. N. Bubnov
    • 1
  • S. P. Solodovnikov
    • 1
  • M. I. Kabachnik
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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