Kinetics and mechanism of hydration of 3-methyl-3-buten-1-ol in aqueous solutions of sulfuric acid

  • R. S. Ryabova
  • G. F. Osipova
  • M. I. Vinnik
Physical Chemistry
  • 27 Downloads

Conclusions

The kinetic regularities of hydration of 3-methyl-3-buten-1-ol in 9.6 to 34% aqueous solutions of sulfuric acid at 25°C were studied. An equation was found for describing the influence of the medium on the value of the effective rate constant of hydration of 3-methyl-3-buten-1-ol.

Keywords

Aqueous Solution Hydration Sulfuric Acid Effective Rate Effective Rate Constant 

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Literature cited

  1. 1.
    S. K. Ogorodnikov and G. S. Idlis, Production of Isoprene [in Russian], Khimiya, Leningrad (1973).Google Scholar
  2. 2.
    K. M. Trenke, M. S. Nemtsov, and M. N. Kiseleva, Zh. Org. Khim.,5, 247 (1969).Google Scholar
  3. 3.
    V. Z. Sharf, L. Kh. Freidlin, V. I. Kheifets, et. al., Neftekhimiya, 13, 832 (1973).Google Scholar
  4. 4.
    Yu. M. Blazhin, S. K. Ogorodnikov, L. N. Volkova, et. al., Zh. Prikl. Khim.,47, 2746 (1974).Google Scholar
  5. 5.
    M. I. Vinnik, Usp. Khim., 1922 (1966).Google Scholar
  6. 6.
    W. T. Jiaque, E. W. Hornung, J. E. Kunzler, and T. R. Rubin, J. Am. Chem. Soc.,82, 62 (1960).Google Scholar
  7. 7.
    R. S. Ryabova, G. F. Oleinik, L. D. Abramovich, et al., Zh. Org. Khim.,12, 499 (1976).Google Scholar
  8. 8.
    G. F. Osipova, R. S. Ryabova, and M. I. Vinnik, Izv. Akad. Nauk SSSR, Ser. Khim., 1001 (1982).Google Scholar
  9. 9.
    V. I. Kheifets, Candidate of Chemical Sciences Dissertation [in Russian], Moscow (1970).Google Scholar
  10. 10.
    M. I. Vinnik, I. S. Kislina, and N. B. Librovich, Dokl. Akad. Nauk SSSR,251, 138 (1980).Google Scholar

Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • R. S. Ryabova
    • 1
  • G. F. Osipova
    • 1
  • M. I. Vinnik
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

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