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Study of the kinetics of the oxidation of palladium(II) by inorganic free radicals in acidic aqueous solutions by pulse radiolysis

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusion

The rate constants for the reactions of OH., NO3 ., and SO4− . with Pd(II) ions in aqueous solutions of the acids have been measured by the pulse radiolysis method. An inner-sphere mechanism of electron transfer.occurs in such reactions.

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Authors and Affiliations

  1. Institute of Physical Chemistry, Academy of Sciences of the USSR, Moscow

    A. V. Gogolev, V. P. Shilov & A. K. Pikaev

Authors
  1. A. V. Gogolev
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  2. V. P. Shilov
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  3. A. K. Pikaev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1001–1004, May, 1988.

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Gogolev, A.V., Shilov, V.P. & Pikaev, A.K. Study of the kinetics of the oxidation of palladium(II) by inorganic free radicals in acidic aqueous solutions by pulse radiolysis. Russ Chem Bull 37, 871–873 (1988). https://doi.org/10.1007/BF00957048

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  • DOI: https://doi.org/10.1007/BF00957048

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