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Diamagnetism of compounds of the B10H12L2 series

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The diamagnetic susceptibilities of a series of decaborane derivatives B10H12L2 were studied by the static magnetic susceptibility method, and the increment ¯χ=125 for the nidocluster ¦B10H12¦ and the atomic increment ¯χB=9.0 in this cluster were derived.

  2. 2.

    The absolute value of χB in the ¦B10H12¦ cluster is substantially greater than χB for noncluster systems (2.7–7.6). This difference confirms the delocalization of the electrons in ¦B10H12¦ and the aromatic character of this nido-cluster.

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Authors and Affiliations

  1. Inorganic Chemistry Institute, Siberian Branch, USSR Academy of Sciences, Novosibirsk

    V. V. Volkov, V. N. Ikorskii & S. T. Dunaev

Authors
  1. V. V. Volkov
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  2. V. N. Ikorskii
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  3. S. T. Dunaev
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 973–976, May, 1988.

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Volkov, V.V., Ikorskii, V.N. & Dunaev, S.T. Diamagnetism of compounds of the B10H12L2 series. Russ Chem Bull 37, 845–848 (1988). https://doi.org/10.1007/BF00957041

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  • DOI: https://doi.org/10.1007/BF00957041

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