Conclusions
-
1.
The direct electrochemical synthesis of various complex fluorides of aluminum, gallium, and indium has been carried out by means of the anodic dissolution of the metal in the presence of a tetraalkylammonium fluoride polyhydrofluoride.
-
2.
The ability of each metal to form fluorine-containing ammonium complexes under the conditions of an electrochemical reaction decreases upon the transition from Al to Tl.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
C. A. Evans, K.-H. Tan, S. P. Tapper, and M. J. Taylor, J. Chem. Soc., Dalton Trans., 988 (1973).
J. J. Habeeb and D. G. Tuck, Chem. Commun., No. 19, 808 (1975).
J. J. Habeeb and D. G. Tuck, J. Chem. Soc., Dalton Trans., 866 (1976).
N. M. Gontmakher, O. N. Nechaeva, V. P. Grigor'ev, et al., Élektrokhimiya,21, 607 (1985).
A. V. Nechaev and A. I. Levin, Izv. Vys. Uchebn. Zaved., Khim. Tekhnol.,15, 464 (1972).
C. A. Evans and M. J. Taylor, Chem. Commun., No. 20, 1201 (1969).
M. Wilkinson and I. J. Worrell, Inorg. Nucl. Chem. Lett.,10, 747 (1974).
W. Lind, L. Waterworth, and I. J. Worrell, Inorg. Nucl. Chem. Lett.,7, 611 (1971).
L. Waterworth and I. J. Worrell, Inorg. Nucl. Chem. Lett.,8, 123 (1972).
M. J. Taylor, D. G. Tuck, and L. Vicrotiano, Can. J. Chem.,60, 690 (1982).
B. H. Freeland, J. L. Hencher, D. G. Tuck, and J. G. Contreras, Inorg. Chem.,15, 2144 (1976).
V. A. Shreider, I. M. Vol'pin, and Yu. E. Gorbunova, Izv. Akad. Nauk SSSR, Ser. Khim., 958 (1988).
Author information
Authors and Affiliations
Additional information
Deceased.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 963–966, May, 1988.
Rights and permissions
About this article
Cite this article
Shreider, V.A., Vol'pin, I.M. Direct electrochemical synthesis of complex fluorides of aluminum, gallium, and indium. Russ Chem Bull 37, 836–838 (1988). https://doi.org/10.1007/BF00957039
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00957039