Abstract
The UV irradiation of branched fluoroolefins leads to the formation of free radicals due to the addition of CF3 to the starting olefin. Branched fluoroolefins containing a fluorine atom at the radical site are incapable of recombination but react with oxygen.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1926–1929, August, 1989.
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Tumanskii, B.L., Solodovnikov, S.P., Bubnov, N.N. et al. Generation of radicals by the photolysis of branched fluoroolefins and their study by EPR spectroscopy. Russ Chem Bull 38, 1771–1774 (1989). https://doi.org/10.1007/BF00956975
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DOI: https://doi.org/10.1007/BF00956975