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Transformations of diethyl phosphite in the presence of Mn2(CO)10

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Upon heating with Mn2(CO)10-BrR systems, diethyl phosphite is partially converted to (EtO)3P(O). Evidence is given for a radical complex mechanism for these transformations.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    M. A. Moskalenko, N. A. Kardanov, A. B. Terent'ev & N. N. Godovikov

Authors
  1. M. A. Moskalenko
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  2. N. A. Kardanov
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  3. A. B. Terent'ev
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  4. N. N. Godovikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1903–1905, August, 1989.

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Moskalenko, M.A., Kardanov, N.A., Terent'ev, A.B. et al. Transformations of diethyl phosphite in the presence of Mn2(CO)10 . Russ Chem Bull 38, 1749–1751 (1989). https://doi.org/10.1007/BF00956967

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  • DOI: https://doi.org/10.1007/BF00956967

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