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Re(III) complexes in the synthesis of platinum acetate complexes and the structure of [PPh3Pt(OAc)2]2

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Reaction of tetrachlorodiacetatodirhenium dihydrate with triphenylphosphineplatinum (II) triacetatoargentate(I) produces a new binuclear platinum complex with acetate bridges, bis[(μ2-acetato)acetatotriphenylphosphine]diplatinum(II). The new complex is characterized by x-ray structural analysis, IR, and PMR spectroscopies. The Re(III) complex in this reaction is not only the source of chloride ions, which are necessary for precipitation of silver, and the acetate acceptor, but also the silver(I) reductant which is oxidized during the reaction to Re(IV).

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    N. Yu. Kozitsyna, M. D. Surazhskaya, T. B. Larina, P. A. Koz'min, A. S. Kotel'nikova & I. I. Moiseev

Authors
  1. N. Yu. Kozitsyna
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  2. M. D. Surazhskaya
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  3. T. B. Larina
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  4. P. A. Koz'min
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  5. A. S. Kotel'nikova
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  6. I. I. Moiseev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1894–1899, August, 1989.

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Kozitsyna, N.Y., Surazhskaya, M.D., Larina, T.B. et al. Re(III) complexes in the synthesis of platinum acetate complexes and the structure of [PPh3Pt(OAc)2]2 . Russ Chem Bull 38, 1739–1744 (1989). https://doi.org/10.1007/BF00956965

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  • DOI: https://doi.org/10.1007/BF00956965

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