Alkaline hydrolysis of phenyl(9-m-carboranyl)bromonium borofluoride: Formation of bis(9-m-carboranyl) ether

  • I. I. Demkina
  • V. V. Grushin
  • T. P. Tolstaya
  • N. I. Vasyukova
Organic Chemistry
  • 36 Downloads

Abstract

Two routes compete in the alkaline hydrolysis of phenyl-9-m-carboranylbromonium borofluoride: nucleophilic substitution with cleavage in the main Br-B bond, giving bis(9-m-carboranyl) ether as the main product, and one-electron reduction with predominant cleavage of the Br-C bond.

Keywords

Ether Hydrolysis Phenyl Main Product Alkaline Hydrolysis 

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Copyright information

© Plenum Publishing Corporation 1990

Authors and Affiliations

  • I. I. Demkina
    • 1
    • 2
  • V. V. Grushin
    • 1
    • 2
  • T. P. Tolstaya
    • 1
    • 2
  • N. I. Vasyukova
    • 1
    • 2
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow
  2. 2.M. V. Lomonosov Moscow State UniversityUSSR

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