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Geminal systems

49. Molecular structure of tetramethoxyhydrazine in a crystal

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

We have determined the molecular structure of tetramethoxyhydrazine in the crystal by x-ray diffraction analysis. The molecule is centrosymmetric with trans orientation of the unshared electron pairs of the N atoms and close to cis-cis conformations of the CONOC fragments.

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Literature cited

  1. A. I. Prokof'ev, V. F. Rudchenko, S. M. Ignatov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 8, 1819 (1989).

    Google Scholar 

  2. R. G. Gerr, A. I. Yanovskii, and Yu. T. Struchkov, Kristallografiya,28, 1029 (1983).

    Google Scholar 

  3. B. V. Ioffe, M. A. Kuznetsov, and A. A. Potekhin, Chemistry of Organic Derivatives of Hydrazine [in Russian], Khimiya, Leningrad (1979).

    Google Scholar 

  4. K. Brink and R. Mattes, Chem. Ber.,118, No. 2, 564 (1983).

    Google Scholar 

  5. M. J. Cardillo and S. H. Bauer, Inorg. Chem.,8, No. 10, 2086 (1969).

    Google Scholar 

  6. L. Radom, W. J. Hehre, and J. A. Pople, J. Am. Chem. Soc.,94, No. 7, 2371 (1972).

    Google Scholar 

  7. H. A. Bent, Chem. Revs.,61, No. 3, 275 (1961); C. C. Levin, J. Am. Chem. Soc.,97, No. 20, 5649 (1975).

    Google Scholar 

  8. M. Tsuboi and J. Overend, J. Mol. Spectrosc.,52, No. 2, 256 (1974).

    Google Scholar 

  9. M. Yu. Antipin, Yu. T. Struchkov, I. F. Shishkov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 10, 2235 (1986).

    Google Scholar 

  10. R. Radom, W. J. Hehre, and J. A. Pople, J. Am. Chem. Soc.,93, No. 2, 289 (1971).

    Google Scholar 

  11. A. J. Kirby, The Anomeric Effect and Related Stereoelectronic Effects at Oxygen, Springer-Velag, Berlin (1983).

    Google Scholar 

  12. D. W. H. Rankin, M. R. Todd, F. G. Riddell, and E. S. Turner, J. Mol. Struct.,71, No. 1, 171 (1981).

    Google Scholar 

  13. B. De B. Darwent, Bond Dissociation Energies in Simple Molecules, National Bureau of Standards, Washington, D. C. (1970).

    Google Scholar 

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    M. Yu. Antipin, Yu. T. Struchkov, V. F. Rudchenko, S. M. Ignatov & R. G. Kostyanovskii

Authors
  1. M. Yu. Antipin
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  2. Yu. T. Struchkov
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  3. V. F. Rudchenko
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  4. S. M. Ignatov
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  5. R. G. Kostyanovskii
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Additional information

For previous communication, see [1].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1825–1828, August, 1989.

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Antipin, M.Y., Struchkov, Y.T., Rudchenko, V.F. et al. Geminal systems. Russ Chem Bull 38, 1672–1675 (1989). https://doi.org/10.1007/BF00956954

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  • DOI: https://doi.org/10.1007/BF00956954

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