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19F NMR spectra and structure for pentafluorophenyl-substituted analogs of the perfluoroallyl cation

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Perfluorinated allyl cations containing a pentafluorophenyl group in positions 1 or 2 are formed in the reaction of SbF5 with the corresponding olefins. The parameters of the19F NMR spectra of these cations were also obtained and discussed. According to the19F NMR data, the pentafluorophenyl groups of these cations are partially removed from the plane of the allyl triad.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelemental Analysis, Academy of Sciences of the USSR, Moscow

    M. V. Galakhov, V. A. Petrov, S. D. Chepik, G. G. Belen'kii, V. I. Bakhmutov & L. S. German

Authors
  1. M. V. Galakhov
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  2. V. A. Petrov
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  3. S. D. Chepik
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  4. G. G. Belen'kii
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  5. V. I. Bakhmutov
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  6. L. S. German
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1773–1777, August, 1989.

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Galakhov, M.V., Petrov, V.A., Chepik, S.D. et al. 19F NMR spectra and structure for pentafluorophenyl-substituted analogs of the perfluoroallyl cation. Russ Chem Bull 38, 1623–1627 (1989). https://doi.org/10.1007/BF00956943

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  • DOI: https://doi.org/10.1007/BF00956943

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