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Effect of the structure of substituted propargyl and allyl alcohols on the rate of their liquid phase hydrogenation on a Pd-Ru alloy membrane catalyst

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

The rates of hydrogenation of substituted propargyl and allyl alcohols in the liquid phase on a Pd-Ru alloy membrane catalyst are described by a two-parameter Taft equation which takes into account the inductive and steric effects of the substituents. The values of the parameters at 363 K with H2 at atmospheric pressure are: ρ*=−0.20, δ=0.10 and ρ*=−1.1, δ=1.3 respectively.

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Authors and Affiliations

  1. A. V. Topchiev Institute for Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    A. N. Karavanov & V. M. Gryaznov

Authors
  1. A. N. Karavanov
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  2. V. M. Gryaznov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1740–1745, August, 1989.

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Karavanov, A.N., Gryaznov, V.M. Effect of the structure of substituted propargyl and allyl alcohols on the rate of their liquid phase hydrogenation on a Pd-Ru alloy membrane catalyst. Russ Chem Bull 38, 1593–1596 (1989). https://doi.org/10.1007/BF00956936

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  • DOI: https://doi.org/10.1007/BF00956936

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