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Interaction of cyclopentadienyl dizircoxane complexes with compounds containing active hydrogen

  • M. Kh. Minacheva
  • É. M. Brainina
  • O. A. Mikhailova
Organic Chemistry

Conclusions

  1. 1.

    Dizircoxane complexes under mild conditions react with compounds containing an active hydrogen in two directions: either cleavage or retention of the dizircoxane group.

     
  2. 2.

    It has been demonstrated that dizircoxane complexes can form stable double compounds: [Cp2ZrYX]2·[Cp2ZrX]2O (X=Y=Cl; X=Br, Y=Cl) and [Cp2ZrX]2O · ROH (R=C6H5, C6H5CH2, X = Cl, Br).

     
  3. 3.

    For [Cp2ZrBr(O2CR)]2°[Cp2Zr(O2CR)2] complexes the IR spectral data indicate the bidentate coordination of acyl ligands.

     

Keywords

Hydrogen Spectral Data Mild Condition Active Hydrogen Bidentate Coordination 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
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    E. M. Brainina and M. Kh. Minacheva, Izv. Akad. Nauk SSSR, Ser. Khim.,1980, 410.Google Scholar

Copyright information

© Plenum Publishing Corporation 1986

Authors and Affiliations

  • M. Kh. Minacheva
    • 1
  • É. M. Brainina
    • 1
  • O. A. Mikhailova
    • 1
  1. 1.Irkutsk Institute of Organic Chemistry, Siberian BranchAcademy of Sciences of the USSRUSSR

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