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Interaction of cyclopentadienyl dizircoxane complexes with compounds containing active hydrogen

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Dizircoxane complexes under mild conditions react with compounds containing an active hydrogen in two directions: either cleavage or retention of the dizircoxane group.

  2. 2.

    It has been demonstrated that dizircoxane complexes can form stable double compounds: [Cp2ZrYX]2·[Cp2ZrX]2O (X=Y=Cl; X=Br, Y=Cl) and [Cp2ZrX]2O · ROH (R=C6H5, C6H5CH2, X = Cl, Br).

  3. 3.

    For [Cp2ZrBr(O2CR)]2°[Cp2Zr(O2CR)2] complexes the IR spectral data indicate the bidentate coordination of acyl ligands.

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Literature cited

  1. É. M. Brainina, R. Kh. Freidlina, and A. N. Nesmeyanov, Dokl. Akad. Nauk SSSR,154, 1113 (1964).

    Google Scholar 

  2. É. M. Brainina, G. G. Dvoryantseva, and R. Kh. Freidlina, Dokl. Akad. Nauk SSSR,156, 1375 (1964).

    Google Scholar 

  3. R. Kh. Freidlina, É. M. Brainina, L. A. Petrashkevich, and M. Kh. Minacheva, Izv. Akad. Nauk SSSR, Ser. Khim.,1966, 1396.

  4. E. M. Brainina and M. Kh. Minacheva, Izv. Akad. Nauk SSSR, Ser. Khim.,1984, 705.

  5. M. Kh. Minacheva and E. M. Brainina, Izv. Akad. Nauk SSSR, Ser. Khim.,1972, 139.

  6. E. M. Brainina, E. V. Bryukhova, B. V. Lokshin, and N. S. Aminov, Izv. Akad. Nauk SSSR, Ser. Khim.,1973, 891.

  7. E. M. Brainina and M. Kh. Minacheva, Izv. Akad. Nauk SSSR, Ser. Khim.,1980, 410.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    M. Kh. Minacheva, É. M. Brainina & O. A. Mikhailova

Authors
  1. M. Kh. Minacheva
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  2. É. M. Brainina
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  3. O. A. Mikhailova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2594–2599, November, 1985.

We express our gratitude to B. V. Lokshin for the discussion and participation in the interpretation of the IR spectra.

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Minacheva, M.K., Brainina, É.M. & Mikhailova, O.A. Interaction of cyclopentadienyl dizircoxane complexes with compounds containing active hydrogen. Russ Chem Bull 34, 2404–2409 (1985). https://doi.org/10.1007/BF00956811

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  • DOI: https://doi.org/10.1007/BF00956811

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