Interaction of cyclopentadienyl dizircoxane complexes with compounds containing active hydrogen

  • M. Kh. Minacheva
  • É. M. Brainina
  • O. A. Mikhailova
Organic Chemistry

Conclusions

  1. 1.

    Dizircoxane complexes under mild conditions react with compounds containing an active hydrogen in two directions: either cleavage or retention of the dizircoxane group.

     
  2. 2.

    It has been demonstrated that dizircoxane complexes can form stable double compounds: [Cp2ZrYX]2·[Cp2ZrX]2O (X=Y=Cl; X=Br, Y=Cl) and [Cp2ZrX]2O · ROH (R=C6H5, C6H5CH2, X = Cl, Br).

     
  3. 3.

    For [Cp2ZrBr(O2CR)]2°[Cp2Zr(O2CR)2] complexes the IR spectral data indicate the bidentate coordination of acyl ligands.

     

Keywords

Hydrogen Spectral Data Mild Condition Active Hydrogen Bidentate Coordination 

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1986

Authors and Affiliations

  • M. Kh. Minacheva
    • 1
  • É. M. Brainina
    • 1
  • O. A. Mikhailova
    • 1
  1. 1.Irkutsk Institute of Organic Chemistry, Siberian BranchAcademy of Sciences of the USSRUSSR

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