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Fluorine-containing heterocumulenes. Communication 22. Synthesis and reactions of fluorine-containing N-acylimidoyl fluorides

  • D. P. Del'tsova
  • Yu. V. Zeifman
  • N. P. Gambaryan
Organic Chemistry
  • 31 Downloads

Conclusions

  1. 1.

    N-Acylimidoyl fluorides of fluorine-containing carboxylic acids were synthesized for the first time.

     
  2. 2.

    Perfluoropropionic acid N-perfluoropivaloylimidoyl fluoride enters 1,4-cycloaddition reactions with nitriles and carbonyl compounds, and by the successive action of CsF and boron trifluoride etherate, converts into the isomeric perfluoro-α-tert-butylpropyl isocyanate.

     

Keywords

Boron Fluoride Carbonyl Nitrile Carboxylic Acid 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1986

Authors and Affiliations

  • D. P. Del'tsova
    • 1
  • Yu. V. Zeifman
    • 1
  • N. P. Gambaryan
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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