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Addition of 2, 2-dichloropropane to 1-hexene and its chemical reactions initiated by systems based on FE(CO)5 and Mn2(CO)10

  • L. N. Kiseleva
  • N. A. Rybakova
Organic Chemistry

Conclusions

  1. 1.

    Addition of 2, 2-dichloropropane to 1-hexene initiated by Fe(CO)5 in combination with HMFA affords 2,4-dichloro-2-methylcotane and 4-chloro-2-methyl-1-octene.

     
  2. 2.

    It has been shown that hydrogenolysis of the C-Cl bond in 2,2-dichloropropane, leading to 2-chloropropane, proceeds efficiently in the presence of Mn2(CO)10 in combination with Et3SiH.

     

Keywords

Et3SiH 
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Literature cited

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Copyright information

© Plenum Publishing Corporation 1986

Authors and Affiliations

  • L. N. Kiseleva
    • 1
  • N. A. Rybakova
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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