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Synthesis of polymeric phosphinocarborane complexes of Rh(I) and their catalytic properties in olefin and diene hydrogenation

  • V. N. Kalinin
  • O. A. Mel'nik
  • A. A. Sakharova
  • T. M. Frunze
  • L. I. Zakharkin
  • N. V. Borunova
  • V. Z. Sharf
Physical Chemistry

Conclusions

  1. 1.

    A method has been developed for the synthesis of polymeric phosphinocarborane complexes of rhodium(I), based on copolymerization of methyl methacrylate with salts of 1-isopropenyl(3)-1,2-dicarbaundecaborate and subsequent interaction of the resulting polymeric matrix with tris(triphenylphosphine)rhodium chloride.

     
  2. 2.

    It has been shown that the phosphinocarborane complexes of rhodium(I) have high activities in the hydrogenation and isomerization of olefins and diolefins.

     

Keywords

Hydrogenation Methyl Chloride High Activity Polymeric Matrix 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1986

Authors and Affiliations

  • V. N. Kalinin
    • 1
    • 2
  • O. A. Mel'nik
    • 1
    • 2
  • A. A. Sakharova
    • 1
    • 2
  • T. M. Frunze
    • 1
    • 2
  • L. I. Zakharkin
    • 1
    • 2
  • N. V. Borunova
    • 1
    • 2
  • V. Z. Sharf
    • 1
    • 2
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow
  2. 2.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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