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Molecular conformations and hydrogen bonds of dimethyl (hydroxymethyl) phosphine oxide

  • R. R. Shagidullin
  • A. V. Chernova
  • R. R. ShagidullinJr
  • T. E. Kron
  • E. N. Tsvetkov
Physical Chemistry
  • 22 Downloads

Conclusions

  1. 1.

    It has been shown by the methods of IR spectroscopy and molecular mechanics that dimethyl (hydroxymethyl) phosphine oxide exists in dilute solutions in CC14, in the form of an equilibrium mixture of conformera.

     
  2. 2.

    An intramolecular hydrogen bond is realized in one of the conformers, and its energy has been estimated from the IR spectra and theoretical data.

     

Keywords

Oxide Hydrogen Spectroscopy Hydrogen Bond Molecular Mechanic 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • R. R. Shagidullin
    • 1
    • 2
  • A. V. Chernova
    • 1
    • 2
  • R. R. ShagidullinJr
    • 1
    • 2
  • T. E. Kron
    • 1
    • 2
  • E. N. Tsvetkov
    • 1
    • 2
  1. 1.Kazan' BranchA. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSRUSSR
  2. 2.Institute of Physiologically Active SubstancesAcademy of Sciences of the USSRChernogolovka

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