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Ring expansion of 1-(chloromethyl)silatrane

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Reaction of alkali metal sucrates and alkoxides with 1-(chloromethyl)silatrane results in expansion of one of the atrane rings to give 2-carba-3-oxahomosilatranes.

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Literature cited

  1. V M. Kilesso, B. N. Stepanenko, and V. I. Kopkov, Third All-Union Conference on Biologically Active Compounds of Silicon, Germanitun, Tin, and Lead (Abstracts of Papers) [in Russian], Irkutsk [1980].

  2. V. S. Vdovin, N. S. Nametkin, K. S. Pushchevaya, and A. V. Topchiev, Izv. Akad. Nauk SSSR, Ser. Khim., 276 (1963).

  3. R. J. Fessenden and J. S. Fessenden, J. Org. Chem.,28, 3940 (1963).

    Google Scholar 

  4. É. Ya. Lukevich and G. I. Zelchan, Zh. Obshch. Khim.,47, 105 (1977).

    Google Scholar 

  5. V. A. Pestrunovich, M. G. Voronkov, G. I. Zelchan, A. F. Lapsin', É. Ya. Lukevich, and L. I. Libert, The Chemistry of Heterocyclic Compounds, Coll. 2 [in Russian], Zinatne, Riga (1970), p. 348.

    Google Scholar 

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1404–1408, June, 1986.

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Kilesso, V.M., Kopkov, V.I., Shashkov, A.S. et al. Ring expansion of 1-(chloromethyl)silatrane. Russ Chem Bull 35, 1276–1280 (1986). https://doi.org/10.1007/BF00956615

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  • DOI: https://doi.org/10.1007/BF00956615

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